Product
n-Heptane
Insight Articles
#PS813
Main Product
Liquid Alkanes
Segment
Chemicals
Main-Family
Alkanes
Sub-Family
Aliphatic Alcanes
Physical State

Liquid

Description

n-Heptane is a straight-chain saturated hydrocarbon (normal alkane) with the molecular formula C₇H₁₆, consisting of seven carbon atoms in an unbranched chain. A colorless, highly volatile and flammable liquid with a faint petroleum-like odor, it occurs naturally in crude oil (0.1–1.9%) and is a major component of straight-run naphtha and gasoline. It is best known industrially as the zero-point reference fuel on the octane rating scale — pure n-heptane is assigned an octane number of 0 by definition, representing the poorest knock resistance — and as a widely used non-polar solvent.

In catalytic naphtha reforming, n-heptane is a key paraffin feedstock that undergoes dehydrocyclization to toluene (C₇H₁₆ → toluene + 4 H₂), making it central to BTX aromatics production.

Industrial uses:

  • Octane rating reference standard: pure n-heptane = 0 RON, used in ASTM knock-test engines to calibrate antiknock performance of all gasoline blends
  • Non-polar solvent: paints, lacquers, rubber cement, adhesives, printing inks, extraction processes
  • Laboratory reagent: non-polar mobile phase in chromatography, extraction solvent in organic synthesis
  • Reformer feedstock: undergoes dehydrocyclization to toluene + 4 H₂ in CCR/semi-regen reformers — the key paraffin-to-aromatic reaction
  • Outdoor stove fuel and pharmaceutical processing solvent

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n-Heptane molecular representations
Identifiers

logo CAS Number
142-82-5
logo EC Number
205-563-8
logo ECHA InfoCard
100.005.054
logo IUPAC Name
Heptane
logo PubChem ID
8900
Chemical Data

Chemical Formula

C7H16

Molecular Weight (g/mol)
100.21
Boiling Point (°C)
98.4
Melting Point (°C)
-90.6
Specific Gravity
0.69
Crude Data

API Gravity
75.07
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Transaction Name Date
Modified by UserPic   Kokel, Nicolas 6/18/2026 3:36 PM
Added by UserPic   Kokel, Nicolas 6/18/2026 3:28 PM