Low-Temperature Methanol Wash Technology (Rectisol) for Syngas Purification

Technology
Low-Temperature Methanol Wash AGR
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Kokel, Nicolas
2/8/2026 2:56 PM



Low-Temperature Methanol Wash AGR (Rectisol) Simplified PFD | Credit:  National Energy Technology Laboratory

Low-temperature methanol wash is a physical acid gas removal (AGR) process that uses refrigerated methanol as a solvent to separate acid gases—primarily CO₂ and H₂S—from industrial gas streams at subzero temperatures. The technology was pioneered in the 1950s when Linde Aktiengesellschaft (Munich, Germany) and Lurgi Mineralöltechnik (Frankfurt, Germany) developed this technology marketed under the Rectisol® trademark.​

 

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Almeida, Luís
2/10/2026 8:19 AM

Process used to absorb H2S acid gas from raw gas streams resulting from gas shift production units. Efficient process for H2S recovery operating at high pressure (50-60 bar) and low temperatures (between -15 and -30 ºC).
 Precautions to be taken in the process are related to clogging of the absorption column trays, the first in the process, and corrosion of the lines under the insulation due to condensation.

I worked with this process for 20 years without any problems and with good cost-efficiency.