Product
Coal-Tar Needle Coke
Names
Coke (coal) Secondary Pitch; Coal Tar-derived Needle Coke
Insight Articles
#PS772
needlecoke coaltarneedlecoke graphite graphiteelectrodes graphiteanodes
Main Product
Coke
Segment
Refined Products
Main-Family
Refinery Residues
Sub-Family
Coal & Petroleum Residues
Physical State

Solid

Description

Coal-tar needle coke is a premium-grade, highly crystalline form of coal-derived coke produced in a delayed coker from highly aromatic coal tar heavy residues. Its name derives from its distinctive needle-like or fibrous microstructure, visible under polarised light microscopy, which reflects the highly oriented, graphene-like carbon layers formed during coking. This long-range microstructural order results in exceptionally low levels of impurities and a characteristically low Coefficient of Thermal Expansion (CTE) — the defining quality parameter of needle coke.

Feedstock

The principal feedstock for coal-tar needle coke is High-Temperature Coal Tar Pitch (HT-CTP) — derived from the carbonisation of coal in blast furnace coke ovens. Coal tar pitch has inherently higher aromaticity than petroleum-derived feedstocks, which favours the development of a highly ordered graphenic microstructure. Its low sulphur content eliminates the puffing risk characteristic of petroleum needle coke. Supply is structurally linked to metallurgical coke oven output, making long-term availability a strategic constraint.

Composition & Properties

Coal-tar needle coke is distinguished by its lower sulphur content and consequently absence of puffing risk during graphitization — a significant processing advantage over petroleum needle coke. However, it carries a higher nitrogen content that is difficult to remove and can affect electrode performance at very high graphitization temperatures. Its denser, more homogeneous microstructure yields better electrical resistivity and CTE performance compared to petroleum needle coke, making it preferred for ultra-high-power (UHP) electrode applications.

Applications

Coal-tar needle coke is a critical precursor for UHP graphite electrodes used in Electric Arc Furnaces (EAF) for steel production, where its superior electrical and thermal properties are particularly valued. It is also used in graphite anodes for lithium-ion batteries, though petroleum needle coke currently dominates this emerging application due to greater supply availability.

Green vs. Calcined

Coal-tar needle coke exits the delayed coker as green coal-tar needle coke, still containing residual volatile matter. It is subsequently calcined at ~1,300°C to remove volatiles, increase real density, and fully develop the graphitic microstructure required for electrode and anode manufacturing. Both green and calcined forms are traded commercially.

Quality Grades & Specifications

Parameter Ultra Premium Super Premium Intermediate Premium
CTE, ×10⁻⁶/°C 0.25 0.35 0.60
Sulphur, wt% Trace 0.1–0.2 0.2–0.4
Nitrogen, wt% Trace <0.3 <0.4
V/Ni, ppm Trace <10 <10
Ash, wt% <0.1 <0.2 <0.3
Real density, g/cm³ 2.15 2.13–2.15 2.13–2.14
Hydrogen, wt% Trace 0.03–0.05 0.03–0.05

Note: Sulphur grades are lower than petroleum needle coke; nitrogen grades are slightly higher.
 

References

  1. Wagner da Silva M., & Clark J. (Nov 2022). Needle coke — overcoming quality challenges in a resurgent market. Digital Refining
  2. Adams R., Frohs W., Jäger H., & Roussel K. Graphite Electrode and Needle Coke Development. Sep 27, 2011
  3. Romey I., Glaser H., Marrett R., & Tillmanns H. (Dec 1983). Production of needle coke from coal tar pitches for graphite electrodes. Germany: N.p.
  4. Zhu Y. et al. (Jun 2020). Preparation and characterization of coal-pitch-based needle coke (Part III): The effects of quinoline insoluble in coal tar pitch. Energy & Fuels, 34(7), 8676–8684. DOI: 10.1021/acs.energyfuels.0c01049
  5. Nippon Steel (Nov 2025). Technical Report No. 134: Pitch Needle Coke for Graphite Electrodes in Steelmaking
  6. AMR (Jan 2026). Needle Coke for EV Batteries Strategic Insights: Analysis 2026 and Forecasts 2033

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Copyright Needle coke | Source: EPIC Milling https://www.epicmilling.com/what-is-needle-coke-and-why-is-it-important/
Identifiers

logo CAS Number
94113-91-4
logo EC Number
302-626-2
logo ECHA InfoCard
100.113.544
logo IUPAC Name
Coke (coal), Secondary pitch
Chemical Data

Chemical Formula

C (mostly carbon)

Sulfur Content (wt%)
0.2
Specific Gravity
2.14
Crude Data

API Gravity
-65.38
Country
Product Settings

Default
Status
A
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Transaction Name Date
Modified by UserPic   Kokel, Nicolas 3/4/2026 10:11 AM
Added by UserPic   Kokel, Nicolas 3/3/2026 9:23 PM